题目：A General Electrochemical C(sp³)−H Amination of Hydrocarbons Suitable for Inactive Alkanes, Alkenes and Alkynes

作者：Zi-Ru Xu (徐紫茹), Hui Gao,*(高慧) Pei-Long Wang,* (王培龙)and Hongyu Wang

单位：Key Laboratory of Green and Precise Synthetic Chemistry and Applications, Ministry of Education; Anhui Provincial Key Laboratory of Synthetic Chemistry and Applications; School of Chemistry and Chemical Engineering, Huaibei Normal University, Huaibei, Anhui 235000, China

摘要：The first example of the electrochemical C(sp³)−H amination of inactive hydrocarbons with sulfoximines was reported. We proposed the concept of an NH₃-induced electrochemical reaction for the ffrst time. Although the electrochemical C(sp³)−H functionalization of inactive linear hydrocarbons is difffcult (especially for alkynes), this reaction is suitable for both linear and cyclic hydrocarbons; the reaction is advantageous because it is green, generates minimal waste (with H₂ as the only byproduct), proceeds without transition metal and external oxidant, and requires mild reaction conditions.

分区情况：SCI一区Top期刊

年、卷、页：2026，28，2355-2360

链接：//pubs.acs.org/doi/10.1021/acs.orglett.6c00002?ref=pdf